Determination of N-Octyl Bicycloheptene Dicarboximide, Pyrethrins, and Butylcarbityl 6-Propylpiperonyl Ether in Technical Materials, Concentrates, and Finished Products by Capillary Gas Chromatography: Collaborative Study (2024)

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Volume 81 Issue 3 1 May 1998

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,

Khanh T Nguyen

Sandoz Agro

, Inc., Animal Health Division, 12200 Denton Dr, Dallas, TX 75234

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,

Richard Moorman

Sandoz Agro

, Inc., Animal Health Division, 12200 Denton Dr, Dallas, TX 75234

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,

Virginia Kuykendall

Sandoz Agro

, Inc., Animal Health Division, 12200 Denton Dr, Dallas, TX 75234

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Journal of AOAC INTERNATIONAL, Volume 81, Issue 3, 1 May 1998, Pages 503–512, https://doi.org/10.1093/jaoac/81.3.503

Published:

14 January 2020

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Received:

13 June 1997

Published:

14 January 2020

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    Khanh T Nguyen, Richard Moorman, Virginia Kuykendall, Collaborators: , Determination of N-Octyl Bicycloheptene Dicarboximide, Pyrethrins, and Butylcarbityl 6-Propylpiperonyl Ether in Technical Materials, Concentrates, and Finished Products by Capillary Gas Chromatography: Collaborative Study, Journal of AOAC INTERNATIONAL, Volume 81, Issue 3, 1 May 1998, Pages 503–512, https://doi.org/10.1093/jaoac/81.3.503

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abstract

Nineteen collaborating laboratories (including the authors') analyzed 6 blind, duplicate pairs of various technical materials, pyrethrum extracts, concentrates, and finished products by split injection capillary gas chromatography (GC) with flame ionization detection. This procedure simultaneously quantitates with speed, ease, accuracy, and precision all 6 insecticidal compounds in pyrethrum: pyrethrin I, jasmolin I, cinerin I, pyrethrin II, jasmolin II, and cinerin II, as well as butylcarbityl 6-propylpiperonyl ether (BPE, the predominant compound in technical piperonyl butoxide, also commonly known as piperonyl butoxide) and both the endo and exo isomers of N-octyl bicycloheptene dicarboximide (MGK 264). Repeatability ranged from 4.28 to 7.22% for total pyrethrins, from 2.41 to 7.04% for BPE, and from 2.20 to 4.91 % for total MGK 264. Reproducibility ranged from 5.22 to 9.71 % for total pyrethrins, from 4.37 to 7.04% for BPE, and from 2.66 to 6.01 % for total MGK 264. The capillary GC method for these insecticidal compounds in technical materials, concentrates, and finished products has been adopted first action by AOAC INTERNATIONAL.

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Determination of N-Octyl Bicycloheptene Dicarboximide, Pyrethrins, and Butylcarbityl 6-Propylpiperonyl Ether in Technical Materials, Concentrates, and Finished Products by Capillary Gas Chromatography: Collaborative Study (2024)

FAQs

What is n octyl bicycloheptene dicarboximide used for? ›

N-Octyl bicycloheptene dicarboximide (MGK 264) is an ingredient in some common pesticides. It has no intrinsic pesticidal qualities itself, but rather is a synergist enhancing the potency of pyrethroid ingredients. It is used in a variety of household and veterinary products.

What is the mode of action of piperonyl butoxide? ›

How does piperonyl butoxide (PBO) work? PBO it not designed to kill insects by itself. Insects have enzymes in their bodies that break down some insecticides. PBO stops some of these enzymes and allows insecticides more time to work.

Is n-octyl bicycloheptene dicarboximide safe for humans? ›

N-octyl bicycloheptene dicarboximide is considered an eye irritant, EPA Toxicity Category III, but only a mild skin irritant, EPA Toxicity Category IV (Reference 1).

What are permethrin and pyrethrins used for chemical control of? ›

Pyrethrum is found in chrysanthemums. Permethrin can kill a broad range of pests, such as fleas, ticks, co*ckroaches, flies, and mosquitoes. Products with permethrin commonly contain piperonyl butoxide (PBO). The PBO increases the permethrin's ability to control insects.

Is pyrethrin safe for humans? ›

In general, pyrethrins are low in toxicity to people and other mammals. However, if it gets on your skin, it can be irritating. It can also cause tingling or numbness at the site of contact.

How do you use pyrethrins and pyrethroids? ›

Some pyrethroids are also used as lice treatments that are applied directly to the head and as mosquito repellents that can be applied to your clothes. A common treatment for scabies is the application of a pyrethroid to the affected skin surface excluding the scalp. The use of these products can lead to exposure.

What is another name for pyrethrins piperonyl butoxide? ›

Pyrethrins/piperonyl butoxide is available under the following different brand names: RID Shampoo, Klout Shampoo, Pronto Shampoo, RID Mousse, A-200 Shampoo, Tisit Gel, Tisit Lotion, and Tisit Shampoo.

What is BHC spray used to control? ›

Benzene hexachloride is used as an insecticide on crops, in forestry, for seed treatment. It is used in the treatment of head and body lice. It is used in pharmaceuticals. It is used to treat scabies.

What is the trade name for dicarboximide? ›

Dicarboximide product perspective
Common NameTrade Name
iprodioneDefence, Ippon, Rapid, Rovral
procymidoneFortress, Sumisclex

What is Pyriproxyfen used for? ›

It is a type of insect growth regulator that affects mostly young insects and eggs. Pyriproxyfen affects many types of insects, including fleas, co*ckroaches, ticks, ants, carpet beetles, and mosquitoes. It has been registered for use in pesticides by the Environmental Protection Agency (EPA) since 1995.

Is permethrin insecticide safe? ›

Depending on the formulation, permethrin is a non-toxic to moderately toxic pesticide. Short-term side effects in sensitive individuals include eye, skin, nose, and throat irritation, and may include breathing problems.

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